Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting          下载免费PDF全文

Matthew S. A. Horstwood  George Gehrels  Simon E. Jackson  Noah M. McLean  Chad Paton  Norman J. Pearson  Keith Sircombe  Paul Sylvester  Pieter Vermeesch  James F. Bowring  Daniel J. Condon  Blair Schoene 《Geostandards and Geoanalytical Research》2016,40(3):311-332

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.  相似文献   

Random forests and evidential belief function-based landslide susceptibility assessment in Western Mazandaran Province,Iran   总被引：1，自引：0，他引：1  

Hamid Reza Pourghasemi  Norman Kerle 《Environmental Earth Sciences》2016,75(3):185

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Punctuated,long-lived emplacement history of the Renard 2 kimberlite,Canada, revealed by new high precision U-Pb groundmass perovskite dating     

Ranger  Ilona M.  Heaman  Larry M.  Pearson  D. Graham  Muntener  Colleen  Zhuk  Volodymyr 《Mineralogy and Petrology》2018,112(2):639-651

Kimberlites are rare volatile-rich ultramafic magmas thought to erupt in short periods of time (<1 Myr) but there is a growing body of evidence that the emplacement history of a kimberlite can be significantly more protracted. In this study we report a detailed geochronology investigation of a single kimberlite pipe from the Renard cluster in north-central Québec. Ten new high precision ID-TIMS (isotope dilution – thermal ionization mass spectrometry) U-Pb groundmass perovskite dates from the main pipe-infilling kimberlites and several small hypabyssal kimberlites from the Renard 2 pipe indicate kimberlite magmatism lasted at least ~20 Myr. Two samples of the main pipe-infilling kimberlites yield identical weighted mean ²⁰⁶Pb/²³⁸U perovskite dates with a composite date of 643.8 ± 1.0 Myr, interpreted to be the best estimate for main pipe emplacement. In contrast, six hypabyssal kimberlite samples yielded a range of weighted mean ²⁰⁶Pb/²³⁸U perovskite dates between ~652-632 Myr. Multiple dates determined from these early-, syn- and late-stage small hypabyssal kimberlites in the Renard 2 pipe demonstrate this rock type (commonly used to date kimberlites) help to constrain the duration of kimberlite intrusion history within a pipe but do not necessarily reliably record the emplacement age of the main diatreme in the Renard cluster. Our results provide the first robust geochronological data on a single kimberlite that confirms the field relationships initially observed by Wagner (1914) and Clement (1982); the presence of antecedent (diatreme precursor) intrusions, contemporaneous (syn-diatreme) intrusions, and consequent (post-diatreme) cross-cutting intrusions. The results of this detailed U-Pb geochronology study indicate a single kimberlite pipe can record millions of years of magmatism, much longer than previously thought from the classical viewpoint of a rapid and short-duration emplacement history.

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The characterisation and origin of graphite in cratonic lithospheric mantle: a petrological carbon isotope and Raman spectroscopic study   总被引：1，自引：1，他引：1  

D. G. Pearson  F. R. Boyd  S. E. Haggerty  J. D. Pasteris  S. W. Field  P. H. Nixon  N. P. Pokhilenko 《Contributions to Mineralogy and Petrology》1994,115(4):449-466

Graphite-bearing peridotites, pyroxenites and eclogite xenoliths from the Kaapvaal craton of southern Africa and the Siberian craton, Russia, have been studied with the aim of: 1) better characterising the abundance and distribution of elemental carbon in the shallow continental lithospheric mantle; (2) determining the isotopic composition of the graphite; (3) testing for significant metastability of graphite in mantle rocks using mineral thermobarometry. Graphite crystals in peridotie, pyroxenite and eclogite xenoliths have X-ray diffraction patterns and Raman spectra characteristic of highly crystalline graphite of high-temperature origin and are interpreted to have crystallised within the mantle. Thermobarometry on the graphite-peridotite assemblages using a variety of element partitions and formulations yield estimated equilibration conditions that plot at lower temperatures and pressures than diamondiferous assemblages. Moreover, estimated pressures and temperatures for the graphite-peridotites fall almost exclusively within the experimentally determined graphite stability field and thus we find no evidence for substantial graphite metastability. The carbon isotopic composition of graphite in peridotites from this and other studies varies from δ¹³ C_PDB = ? 12.3 to ? ?3.8%o with a mean of-6.7‰, σ=2.1 (n=22) and a mode between-7 and-6‰. This mean is within one standard deviation of the-4‰ mean displayed by diamonds from peridotite xenoliths, and is identical to that of diamonds containing peridotite-suite inclusions. The carbon isotope range of graphite and diamonds in peridotites is more restricted than that observed for either phase in eclogites or pyroxenites. The isotopic range displayed by peridotite-suite graphite and diamond encompasses the carbon isotope range observed in mid-ocean-ridge-basalt (MORB) glasses and ocean-island basalts (OIB). Similarity between the isotopic compositions of carbon associated with cratonic peridotites and the carbon (as CO₂) in oceanic magmas (MORB/OIB) indicates that the source of the fluids that deposited carbon, as graphite or diamond, in catonic peridotites lies within the convecting mantle, below the lithosphere. Textural observations provide evidence that some of graphite in cratonic peridotites is of sub-solidus metasomatic origin, probably deposited from a cooling C-H-O fluid phase permeating the lithosphere along fractures. Macrocrystalline graphite of primary appearance has not been found in mantle xenoliths from kimberlitic or basaltic rocks erupted away from cratonic areas. Hence, graphite in mantle-derived xenoliths appears to be restricted to Archaean cratons and occurs exclusively in low-temperature, coarse peridotites thought to be characteristic of the lithospheric mantle. The tectonic association of graphite within the mantle is very similar to that of diamond. It is unlikely that this restricted occurrence is due solely to unique conditions of oxygen fugacity in the cratonic lithospheric mantle because some peridotite xenoliths from off-craton localities are as reduced as those from within cratons. Radiogenic isotope systematics of peridotite-suite diamond inclusions suggest that diamond crystallisation was not directly related to the melting events that formed lithospheric peridotites. However, some diamond (and graphite?) crystallisation in southern Africa occurred within the time span associated with the stabilisation of the lithospheric mantle (Pearson et al. 1993). The nature of the process causing localisation of carbon in cratonic mantle roots is not yet clearly understood.  相似文献   

Book reviews     

Boulding  Kenneth E.  Rosenberg  Norman J.  Harvey  L. D. Danny 《Climatic change》1985,7(4):461-466

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Effect of treatment with reserpine on the change in filtration rate of Mytilus edulis subjected to dissolved copper     

Richard Howell  Alasdair M. Grant  Norman E.J. Maccoy 《Marine pollution bulletin》1984,15(12):436-439

Exposure of specimens of Mytilus edulis to dissolved copper leads to a fall in the filtration rate measured in whole animals. The copper concentration leading to a 50% reduction in the filtration rate was found to be 0.094 mg I⁻¹. This effect was abolished on depletion of the monoamine content of the animal using reserpine. It is suggested that there may be a chemosensory mechanism present in the animals which responds to increased levels of metals in the seawater leading to a reduction in the rate of ciliary beating and mediated via the branchial nerve.  相似文献   

RbSr and KAr ages of paleozoic glauconites from Ohio—Indiana and Missouri,U.S.A.     

Norman K. Grant  Thomas E. Laskowski  K.A. Foland 《Chemical Geology》1984,46(3):217-239

Glauconite pellets from the Lower Silurian Brassfield Formation on both limbs of the Cincinnati Arch in Ohio and Indiana give a RbSr age of 370 ± 11 Ma, which is substantially younger than the stratigraphic age of the formation. The age is concordantcwith conventional KAr ages of 355 ± 6 and 368 ± 5 Ma for two of the same glauconites. Concordant ages were also obtained from the Viburnum Trend in Missouri, where glauconite pellets from the Davis Formation in an ore-zone collapse structure into the underlying Bonneterre Formation give a RbSr age of 387 ± 21 Ma and conventional KAr ages of 368 ± 5 and 369 ± 5 and 369 ± 5 Ma. A third suite of glauconite from the Bonneterre Formation in the Old Lead Belt ～ 10 km from the nearest ore body has given a RbSr age of 423 ± 7 Ma and slightly older conventional KAr ages of 434 ± 6, 445 ± 6 and 441 ± 11 Ma.Because these glauconite-bearing rocks have been buried to depths of less than 1 km, thermal resetting of the RbSr and KAr systematics appears unlikely. The initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios of the RbSr isochrons are similar to the ratios for vein- and vug-filling dolomite and calcite. This is consistent with resetting of the RbSr and KAr systems during diagenetic changes which included the isotopic equilibration (perhaps by cation exchange) of the Sr in the glauconite with that in the diagenetic and Mississippi Valley-type ore fluids. This interpretation implies that the age of the Mississippi Valley-type mineralization in the Viburnum Trend is Devonian rather than Carboniferous—Permian as has been inferred from paleomagnetic measurements.Cation-exchange experiments with a dilute Sr-bearing solution and an artificial oilfield brine indicate that glauconite adsorbs large amounts of Sr, some of which is sufficiently strongly attached to the glauconite lattice as to resist leaching with ammonium acetate. The introduction of this strongly attached Sr may be the first step in the resetting of the RbSr systematics of glauconite by cation exchange.  相似文献   

The increasing CO2 concentration in the atmosphere and its implication on agricultural productivity II. Effects through CO2-induced climatic change     

Norman J. Rosenberg 《Climatic change》1982,4(3):239-254

In a prior paper (Part I), the point was made that, assuming an unchanged climate, water use efficiency in agricultural crop production will likely be favored by the increase in CO₂ concentration projected to occur within the next half century. Since climatic changeis likely to result from the CO₂ concentration increase, its possible impacts on agricultural productivity must also be considered. An attempt to do so, using the Great Plains region of North America as a case study, is reported in this paper (Part II). A number of climatic models predict significant increases in surface temperature. Manabe and Wetherald's (1980) model provides the most specific projections for a hypothetical Northern hemisphere continent. That model also predicts an intensification of the hydrologic cycle with rainfall distribution altered so that some zones will receive more and some less as a result of a doubling in the atmospheric CO₂ concentration. The zone between 37 and 47° N latitude will suffer a reduction in availability of soil moisture. A number of regression models of grain yield as a function of temperature and precipitation have been used to anticipate the impacts of the projected climatic changes. The value of this approach is questioned. An alternative approach - the study of the migration of major agricultural crops across strong climatic gradients - is proposed. Changes in the geographical distribution of the hard red winter wheat zone in North America provide an example. The point is also made that factorscurrently limiting food production must be considered in order to predict the possible impacts of any given climatic change. In the central Great Plains today, the energy consumed by evapotranspiration often exceeds that supplied by net radiation since sensible heat advection from dryer regions to the south and west provides a major additional input of energy. If, as models project, the excess of precipitation over evaporation increases south of 37° N, the advection of sensible heat and, hence, the rates of evapotranspiration and degree of water stress on growing plants could be reduced in the adjacent regions to the north. Published as Paper No. 6123, Journal Series, Nebraska Agricultural Experiment Station. The work reported was conducted under Regional Research Project 11-033 and Nebraska Agricultural Station Project 11-049. George Holmes Professor of Agricultural Meteorology, Center for Agricultural Meteorology and Climatology, Institute of Agriculture and Natural Resources, University of Nebraska, Lincoln, Nebraska, 68583-0728.  相似文献   

Characteristics of air flow above and within soybean canopies     

Dennis D. Baldocchi  Shashi B. Verma  Norman J. Rosenberg 《Boundary-Layer Meteorology》1983,25(1):43-54

Air flow was observed above and within canopies of a number of kinds of soybeans. The Clark cultivar and two isolines of the Harosoy cultivar were studied in 1979 and 1980, respectively. Wind speed above the canopy was measured with cup anemometers. Heated thermistor anemometers were used to measure air flow within the canopy. Above-canopy air flow was characterized in terms of the zero-plane displacement (d), roughness parameter (z _o) and drag coefficient (C _d). d and z _o were dependent on canopy height but were independent of friction velocity in the range 0.55 to 0.75 m s^?1 · C _d for the various canopies ranged from 0.027 to 0.035. Greater C _d values were measured over an erectophile canopy than over a planophile canopy. C _d was not measurably affected by differences in leaf pubescence. Within-canopy wind profiles were measured at two locations: within and between rows. The wind profile was characterized by a region of great wind shear in the upper canopy and by a region of relatively weak wind shear in the middle canopy. Considerable spatial variability in wind speed was evident, however. This result has significant implications for canopy flow modeling efforts aimed at evaluating transport in the canopy. In the lower canopy, wind speed within a row increased with depth whereas wind speed between two rows decreased with depth. The wind speeds at the two locations tended to converge to a common value at a height near 0.10 m. The attenuation of within-canopy air flow was stronger in canopies with greater foliage density. Canopy flow attenuation seemed to decrease with increasing wind speed, suggesting that high winds distorted the shape of the canopy in such a manner that the penetration of wind into the canopy increased.  相似文献   

Radiocarbon dating of Danube Delta deposits     

Nicolae Panin  Stefana Panin  Norman Herz  John E. Noakes 《Quaternary Research》1983,19(2):249-255

The Holocene history of the Danube Delta has been studied using ¹⁴C analyses of faunal material. The principal phases of development include: (1) initial Letea Caroarman spit, 11,700–9800 yr B.P. in its central part, 8800-5500 yr B.P. in its southern part; (2) Sf. Gheorghe I Delta, 8900-7200 yr B.P.; (3) Sulina Delta, 7200-2000 yr B.P., and (4) Sf. Gheorghe II Delta-Chilia Delta 2000 yr B.P.-present. Other smaller-scale features have also been dated, including secondary deltas (Co?na and Sinoe Deltas) and littoral bars. Age determinations carried out on whole samples were erratic and it was found that individual species had to be separated and dated. In all cases, the older dates were of transported material whereas the younger dates gave the true age of the formation.  相似文献